- His great-grandfather was the second cousin of Ernesto 'Che' Guevara's mother.
- Is part of a tango band called "El Yotivenco", with Blas Alberti and Juan Pablo Díaz Hermelo.
- Lives in Ingeniero Maschwitz, province of Buenos Aires.
- Father of, with Ludmila Romero, Olivia de la Serna (b. February 2019) and Estanislao de la Serna (b. February 2020).
- Father, with Erica Rivas, of Miranda de la Serna (born 2000).
- Ex-boyfriend of Contra las cuerdas (2010)'s co-star Soledad Fandiño (January-October 2011).
- Was in a relationship with actress Pilar Gamboa from 2012 to 2016. They met on the set of Tiempos Compulsivos (2012).
- Was in a relationship with Ludmila Romero from 2017 to 2021.
- He couldn't be at the Independent Spirit Awards where he won 'Best Debut Performance' for The Motorcycle Diaries (2004). So his co-star Gael García Bernal accepted on his behalf.
- Was in a relationship with actress Erica Rivas (September 1999-2010).
- Grew up in Buenos Aires's neighborhood Belgrano.
- Brother of Manuel De la Serna.
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