Boiler Rajshahi
Boiler Rajshahi
Definition of Boiler
• A Boiler is a closed vessel in
which water or other fluid is
heated. The fluid does not
necessarily boil.
Phenomenon Water (Steam Generation)
Sensible Latent Heat Sensible Latent Heat Sensible
Heat of fusion Heat of vaporization or condensation Heat
150oC
Water boiling
100oC
Temperature oC
Steam Condensing
Change of State
Ice Melting
Steam
0oC Water
Ice Freezing
ICE Change of State
-17.77oC
37 kJ 334 kJ 418 kJ 2250 kJ 97.4 kJ
Heat (kJ) per kg of Water
Specific Latent Heat of Fusion and Solidification for Water
Receives FORMS 1 kg of
1 kg of Ice 334.9 kJ of
Water at
at 0OC Heat
FORMS GIVES UP 0OC
1 kg of Receives FORMS 1 kg of
2256.9 kJ of
Water at Steam at
Heat
100OC FORMS GIVES UP 100OC
400 374.15°C
CRITICAL POINT
350° 22123 kPa
15000 kPa
300° 10000 kPa
250° 5000 kPa
3000 kPa
200°
0° Pressure kPa
© Kshirod Mohan Bose, XEN, GPS +8801711076856, kshirod124@[Link]
• Power required to be generated
• Operating Pressure
• Fuel-quality and type
• Water availibility and its quality
• Probable load factor
• Location of the powerhouse or process
plants
• Cost of operations and maintenance
• Cost of installations and erection
• Availibility of floor space
It should be capable of quick start-up
For power
Plant
For Plant
Boiler Process
Locomotive
Mobile
boiler
Marine
Based on Tube and Furnace Position
On the basis of
On the basis of
furnace Position
Tube of Boiler
of Boiler
Internally
Water Tube
Fired
Externally
Fire Tube
Fired
Coal Fired Boiler
Induced Draught
Boiler
Balanced
© Kshirod Mohan Bose, XEN, GPS Draught Boiler
+8801711076856, kshirod124@[Link] 12
Boiler
16
Heat Recovery Steam Generator (HRSG)
HP:Higpressure
Stack
LP Super-heated
Steam
IP Super-heated HP FWP IP FWP
IP HP
Steam
OTC OTC
Deaerator
HP Super-heated Steam
Kshirod Mohan Bose +8801711076856, kshirod124@[Link]
• Application: Industrial process, Steam turbine drive (< 50
MW)
• Multi Fuels: Oil, Gas and Solid
• Steam Capacity up to 200 Ton/hr
• Design Pressure up to 120 Bar
• Design Temperature up to 500o C
• Site assembly
• Consideration of Industrial Boiler:
• Multi-fuel Burning capability
• Waste Fuel Utilization (biomass, waste acid, sludge, etc.)
• Cogeneration Potential to maximize heat from their fuel
Burner Position
Economizer
Lower Header
Stack
Platen SH
Con. SH 1
Con. SH 2
RH 2
RH 1
Econ.
Regenerative Air
Radiant SH FW Heater
FD Fan
FUEL Air
ID Fan
Furnace Boiler of 210 MW Ghorashal Power Station
Sub- critical, Super High Pressure, Water Tube,
Balanced Draft with Condensing Turbine
© kshirod124@[Link] 24
• Application: Electric Utility
• Fuels: Pulverized Coal
• Steam Capacity up to 2,500 Ton/hr
(800 MW)
• Design Pressure up to 253 Bar
• Design Temperature up to 565o C
• Higher efficiency (no steam drum, no
blow-down system)
• Feed water quality is major concern
• Site assembly
Sub Critical
170 540 35 900
(Maximum Capacity 500 MW)
35
Unburnt &
Unaccounted Loss Stack Loss & Radiation Loss AIR ENERGY IN
Hot Air
Air Heater
Re-Heater Economizer
Unburnt &
Air (Electrical)
Unaccounted
Circulation of Water and Steam in Boiler
Natural Circulation • Forced Circulation
STEAM (Ms)
Ms
WATER Mw
(Mw)
COLD SIDE
Steam +
DOWNTAKE or
DOWNCOMER
Water
HOT SIDE
HOT SIDE
COLD SIDE
ORIFICE
CIRCULATING PUMP 38
© Kshirod Mohan Bose, XEN, GPS +8801711076856, kshirod124@[Link]
⚫ Furnace
– radiation mode
Spaced SH
Radiant SH
Evap.
⚫ Radiant (Platen) Super-heater
– luminous radiation mode
Econ.
– non-luminous radiation mode
– convection mode
⚫ Convective (Spaced) Super-heater
– non-luminous radiation mode
– convection mode
⚫ Evaporator (Boiler Bank)
Furnace
– convection mode
⚫ Economizer
– convection mode
Boiler Drum
• Boiler Drums can only be tested in Shop.
• The Drum pressure is higher than water-wall and
External View super-heater.
• Test pressure = 1.2/1.3 x Drum Working Pressure
Drum Internals
Steam Separation Procedure
Steam Out for Super Heating
Water
Level
Gauge
Cyclone
Feed Water In Separator
Cyclone Separators
Water Level
Pressure Components (Mainly Water Circuit)
Economizer
Attemparators
RELIEF VALVE
59
© Kshirod Mohan Bose, XEN, GPS +8801711076856, kshirod124@[Link]
WATER GAUGES and INDICATORS
CL
NWL
O
AIR
AIR
AIR
• Axial Flow
Common Types of Fans
De-aerator
Feed Pump
• Multi- stage
centrifugal pump
• Driven by Motor or
Turbine
• May be configured as
1 100%, 2 100%, 3
66%
Type of
Maintenance:
Corrective /
Preventive
Break Down
Maintenance
Maintenance
Diagnostics &
Type of Fuel
Expert System
Maintenance
Reliability Needed
Planning Replacement Parts
availability
Onside
Reserve
Maintenance Utilization Need Environment
Requirement
Capability
73
MAINTENANCE PLANNING
PURPOSE OF
TREATMENT- DOZING
❑ Reduce Corrosion ❑ Hydrazine Dozing (N2H4) as
❑ Reduce Scale Oxygen Scavenger to remove
dissolve Oxygen form Boiler
❑ To reduce force trip & outage Feed Water. (Minimize
Corrosion)
❑ To increase efficiency of Boiler
❑ Ammonium Phosphate Dozing
❑ To reduce Deposition in for Maintaining PH through
Turbine & Super heater (Carry neutralization of acid
Over). (Normally PH of Boiler water is
9 to 11).
Introduction
81
Different Failure Mode
Failure Mode of Boiler Tubes according to EPRI
2%
24%
24%
9%
11%
6%
4%
20%
Long term Over heating Creep Short Term Overheating Thermal Fatigue
Mechanical Overload Corrosion Form of Corrosion Manufacturing Defects
82
• Corrosion Fatigue
Leading • Fly Ash Erosion
• Under Deposit Mechanisms
mechanism • Hydrogen Damage and Acid Phosphate
Corrosion
83
of boiler tube • Long Term Overheating/Creep
86
Corrosion Fatigue
87
Corrosion Fatigue
Microstructure features
88
Corrosion Fatigue Prevention
Controlling cyclic Controlling
Boiler redesign
tensile stresses environmental factors
Reducing or
Extending start-up and
eliminating cyclic Contouring of welds
shutdown times
operation of the boiler
Redesign of tube
attachments
89
Corrosion Fatigue
91
Fly Ash Erosion
• Frequently causes smoothly
polished surfaces.
• In other cases, irregular flow
marks and grooving are
produced by eddies around
slag encrustations, hangers,
brackets
• In extreme cases, thinning can
cause rupture.
92
Fly Ash Erosion
• Close inspection of the rupture
site often reveals thinning of the
external surface and no
overheating or corrosion
• Metallographic examination
may reveal microscopic plastic
deformation on thinned
surfaces
93
Under Deposit Mechanism
• Hydrogen damage
• Acid phosphate corrosion
• Both may be originated from deposits
94
Hydrogen Damage
• Direct result of electrochemical
corrosion reactions in which
hydrogen in the atomic form is
liberated
• Typically confined to internal
surfaces of water-carrying tubes
that are actively corroding
• Damage usually occurs in regions
of high heat flux; beneath heavy
deposits; in slanted or horizontal
tubes; and in heat-transfer regions
at or adjacent to backing rings at
welds, or near other devices that
disrupt flow
95
Hydrogen Damage
• Corrosion reactions → production H atoms
• Can occur in high-pH or a low-pH corrosion
Metal gouging
97
Hydrogen Damage
• It is difficult to visually identify hydrogen damage
prior to failure
• areas that have sustained either high-pH or low-pH
corrosion should be considered suspect.
• Ultrasonic thickness checks may disclose corroded
areas that should be considered suspect
• Boiler water contamination → condenser in leakage
Fresh water source → base substance → high pH corrosion
Seawater source → acidic substance → low pH corrosion
98
Hydrogen Damage
Prevention/elimination:
• Reduce the amount of available free sodium hydroxide
• Prevent inadvertent release of regeneration chemicals from makeup-water
demineralizers
• Prevent condenser in-leakage
• Prevent contamination of steam and condensate by process streams
• Prevent departure from nucleate boiling
• Prevent excessive water-side depositions
• Prevent waterline formation
99
Hydrogen Damage
100
Acid Phosphate Corrosion
• On-going problem in phosphate-
treated boilers, especially as
pressures have increased
• The phosphates hideout in deposits
as temperatures increase
• The equilibrium chemistry for the
phosphates depends on the boiler
pressure and on whatever other
additives are present in the water, so
the treatment program needs to be
tailored to the individual boiler
conditions
101
Acid Phosphate Corrosion
• Phosphate corrosion results in localized attack under deposits,
producing gouges, grooves or depressions similar to those resulting
from caustic.
• Hideout is associated with increased pH in the boiler water, so high-
pH related corrosion may be reported even though the conditions
within the deposits may be acidic
• The attack occurs where a deposit or scale has already formed
102
Acid Phosphate Corrosion
• Sodium phosphate salts have retrograde solubility→
precipitate from solution as the temperature
increases
• The phosphate may react with the iron and magnetite
to form maricite, NaFePO4
103
Acid Phosphate Corrosion
• In phosphate corrosion, there
is typically a porous deposit
with an inner layer of the
deposit which is white or
grey. This light-colored
compound may appear to be
crystalline and can be
identified via X-ray diffraction
as maricite
• Reddish streaks of hematite
may also be present in the
deposit. Iron phosphate may
also be found
104
Acid Phosphate Corrosion
Prevention:
• Maintain equilibrium phosphate control.
• Chemically clean the waterside to remove deposit build-ups.
• Reduce flow disruptions in tubes.
• Reduce burner impingement.
105
Long Term Overheating
• Long-term overheating is a
condition in which metal
temperatures exceed design
limits for days, weeks, months, or
longer.
• Rupture caused by normal
internal pressure becomes more
likely as temperatures rise.
• Long-term overheating depends
on temperature, length of time
at temperature, and tube
metallurgy.
106
Long Term Overheating
• Occur in water- and steam cooled tubes such as water walls, down
comers, screen tubes, superheaters, reheaters, and roof tubes →
rarely occurs in economizers and floor tubes
• 90% of failures caused by long-term overheating occur in super-
heaters, re-heaters, and wall tubes
• Failures usually occur in relatively broad areas and involve many
tubes
107
Long Term Overheating
• Rupture is preceded by bulging
• Many times bulging results because hot-face (hot-side) temperatures
are not uniform and local regions develop hot spots.
• Bulging usually causes spalling of deposits at the bulge site, which
reduces metal temperature locally
• Bulging increases surface area, allowing a greater fire-side heat input
locally
• Metal temperature is higher at bulges than in the surrounding metal
• Continued existence of bulges is sufficient to cause overheating even
if associated deposits are removed
108
Long Term Overheating
109
Long Term Overheating
• One sign of long-term
overheating : thick, brittle,
dark oxide layer on both
internal and external
surfaces
• Excessive metal temperature
→ excessive thermal
oxidation
110
Long Term Overheating
112
Long Term Overheating
Prevention:
• Removal of a chronic system defect
• Regular inspection on Headers, U-bends, long horizontal runs, and the
hottest areas
• Excess deposits should be removed by chemical or mechanical
cleaning
• Periodic checking on firing procedures, Btu value of fuels, and in-
service furnace temperatures near overheated areas
• Proper water treatment
• Proper boiler operation
113
Long Term Overheating
114
Short Term Overheating
• Occurs when the tube
temperature rises above design
limits for a brief period
• Instantly, metal temperatures are
at least 454 C and often exceed
730 C
• Depending on temperature, failure
may occur in a very short time
• Failure is usually caused by a boiler
operation upset
• Other cause : partial or total tube
pluggage and insufficient coolant
flow due to upset conditions
and/or excessive fire-side heat
input
115
Short Term Overheating
• Confined to steam- and water-cooled tubes including downcomers,
waterwalls, roofs, screens, superheaters, and reheaters
• Low water level → often occur near the top of waterwalls near steam
drums
116
Short Term Overheating
• Distinct identification by
microstructure examination
• Uniform tube expansion,
absence of significant internal
deposits, absence of large
amounts of thermally formed
magnetite, and violent rupture.
• Bulging, fish mouth
117
Short Term Overheating
Example of microstructure transformation
due to short term overheating
119
Short Term Overheating
Prevention
• Upset elimination
• Inspection & cleaning → reduce tube plugging
• Monitoring drum water level, firing procedures, and blowdown and
start-up procedures
120
Short Term Overheating
121
Sootblower Erosion
• Damage occurs near or in the
direct path of soot-blower
discharge
• Superheater tubing is usually
attacked
• Common damage locations:
tubes along the path of
retractable soot blower, tubes
nearest wall entrances of
retractable blowers
122
Sootblower Erosion
• Common cause of erosion in
boilers is soot-blower attack
• Physical abrasion and
accelerated oxidation cause
metal loss
• Damage can be accelerated by
fly ash entrained in the high-
velocity jet stream directed
against the tube surface.
• Erosive thinning often leads to
tube rupture
• Soot-blower erosion is caused
by improper blower alignment
and improper operation
123
Sootblower Erosion
• Attacked surfaces are locally thinned
• Close visual observation of thinned
surfaces will often show very shallow
wavelike striations
• The striations will be aligned
perpendicularly to steam flow across
the surface
• Bulging will usually be absent in
internally pressurized tubes suffering
erosion.
• Rupture is usually longitudinal
• Rupture edges will be thin and ragged
124
Sootblower Erosion
Prevention:
• Proper soot-blower operation, alignment, and function
• Periodic inspection of nozzle position and alignment
• Elimination of moisture in blowing steam can be accomplished by
allowing adequate steam warm-up and providing for adequate
drainage of steam supply lines
• Metalizing, welding, and plasma spray techniques can increase wall
thickness in affected areas and thus prolong tube life
125
Fireside Corrosion
• Coal ash corrosion
• Waterwall fireside corrosion
126
Coal Ash Corrosion
• High-temperature, liquid-phase
corrosion phenomenon that
occurs on metals whose surface
temperatures are in the range of
566 C to 732 C
• Confined to super-heater and re-
heater sections of the boiler
127
Coal Ash Corrosion
• During coal combustion, minerals in the coal are exposed to high temperatures,
causing release of volatile alkali compounds and sulfur oxides.
• Coal-ash corrosion occurs when fly ash deposits on metal surfaces where
temperatures range from 566 to 7320C. With time, the volatile alkali compounds
and sulfur compounds condense on the fly ash and react with it to form complex
alkali sulfates such as K3Fe(SO4)3 and Na3Fe(SO4)3 at the metal/deposit interface.
• The molten slag fluxes the protective iron oxide covering of the tube, exposing
the metal beneath to accelerated oxidation.
• Reduction of wall thickness by this corrosion mechanism effectively increases
stresses through the thinned wall. These increased stresses, coupled with high
metal temperatures, may lead to final failure by stress rupture.
128
Coal Ash Corrosion
• Slag buildup on the tube wall and the associated metal loss
• Austenitic stainless steel tubes → a pockmarked surface
appearance.
• Low-alloy carbon steel tubes typically show a pair of flat zones
of metal loss that are located on both sides of the leading face
of the tube at orientations of 30 to 45°
• Corroded surfaces have a grooved or roughened appearance
129
Coal Ash Corrosion
• The highest corrosion rates are
generally found in tubes having
the highest steam temperatures,
e.g. the outlet tubes of radiant
superheater or reheater.
• Maximum rate of attack is in the
temperature range where molten
sulfates are soluble
• At higher temperatures, the
corrosion rate decreases rapidly
because of thermal
decomposition of the corrosives
130
Coal Ash Corrosion
• Associated with a sintered or
slag-type deposit consisting of
three distinct layers
• Outer layer : bulky porous fly
ash
• Middle layer : whitish, water-
soluble alkali sulfates
• Inner layer: glassy black iron
oxides and sulfides at the metal
surface Most severe metal loss
• Can occur with any bituminous
coal but is more probable with
coals containing more than 3,5
% S and 0.25% Cl
131
Coal Ash Corrosion
Prevention:
• Lower steam temperature
• Use a material with better resistance i.e., higher chromium, silicon, or
aluminum content
• Thickness surveys → the extent and severity of the attack.
• If corrosion is not severe, economic solutions may include periodic tube
replacement, specification of thicker tube walls, use of thermal spray
coatings, or weld overlay
• Periodic cleaning of drainable superheater and reheater sections to
prevent buildup of internal scale.
• Redesign of affected areas to reduce heat-transfer rates
132
Coal Ash Corrosion
133
Coal Ash Corrosion
134
Coal Ash Corrosion
135
Coal Ash Corrosion
136
Waterwall Fireside Corrosion
• May develop when incomplete fuel
combustion occurs, causing release
of volatile sulfur compounds,
forming pyrosulfates.
• Sodium and potassium pyrosulfates
(Na2S2O7 and K2S2O7) have
melting points of 427 or less, and
both have a high chemical activity.
• These molten slags may flux the
protective magnetite on tube
surfaces, causing accelerated metal
deterioration along the crown of
the tube
137
Waterwall Fireside Corrosion
• Insufficient oxygen in the burner zone → primary factor in
development of waterwall corrosion.
• Poor combustion conditions and steady or intermittent flame contact
with the furnace walls, combined with coals that are capable of
forming an ash with a low fusion temperature, produce a hot, fuel-
rich corrosion environment.
138
Waterwall Fireside Corrosion
140
Waterwall Fireside Corrosion
141
Other Failure Mode
142
Other Failure Mode
143
Other Failure Mode
144
Name of Place Type of Problem Remark/ Cause
Two surface
cracks
Cluster
Magnetic Field
From Test Coil
Magnetic Field
From
Eddy Currents
Crack
Eddy Currents
Radioactive Source
Electrons
+ -
X-ray Generator or
Radioactive Source
Creates Radiation
X-ray film
Radiation
Penetrate
the Sample
Method Applicability
Tube section • The preferred repair method
replacement • Consists of replacing tube section with one of same material and dimensions.
Grind out and re-weld • Applicable for small defects such as pin-hole leaks.
• Vee-preparation and re-weld.
Pad welding • Should only be used in an emergency as repeat failures are nearly always
guaranteed. Should be replaced at next major outage.
• Involves mechanically closing the rupture to original contour, veeing a weld
groove and re-welding.
Window welding May be required if access all around the tube is limited. Should be used only as a
temporary measure with full replacement at next outage.
Example of window
welding