Many quantum algorithms have daunting resource requirements when compared to what is available today. To address this discrepancy, a quantum-classical hybrid optimization scheme known as 'the quantum variational eigensolver' was developed (Peruzzo et al 2014 Nat. Commun. 5 4213) with the philosophy that even minimal quantum resources could be made useful when used in conjunction with classical routines. In this work we extend the general theory of this algorithm and suggest algorithmic improvements for practical implementations. Specifically, we develop a variational adiabatic ansatz and explore unitary coupled cluster where we establish a connection from second order unitary coupled cluster to universal gate sets through a relaxation of exponential operator splitting. We introduce the concept of quantum variational error suppression that allows some errors to be suppressed naturally in this algorithm on a pre-threshold quantum device. Additionally, we analyze truncation and correlated sampling in Hamiltonian averaging as ways to reduce the cost of this procedure. Finally, we show how the use of modern derivative free optimization techniques can offer dramatic computational savings of up to three orders of magnitude over previously used optimization techniques.

This tutorial introduces the theoretical and experimental basics of electromagnetically induced transparency (EIT) in thermal alkali vapors. We first give a brief phenomenological description of EIT in simple three-level systems of stationary atoms and derive analytical expressions for optical absorption and dispersion under EIT conditions. Then we focus on how the thermal motion of atoms affects various parameters of the EIT system. Specifically, we analyze the Doppler broadening of optical transitions, ballistic versus diffusive atomic motion in a limited-volume interaction region, and collisional depopulation and decoherence. Finally, we discuss the common trade-offs important for optimizing an EIT experiment and give a brief 'walk-through' of a typical EIT experimental setup. We conclude with a brief overview of current and potential EIT applications.

In this work we present theoretical calculations and analysis of the vibronic structure of the spin-triplet optical transition in diamond nitrogen-vacancy (NV) centres. The electronic structure of the defect is described using accurate first-principles methods based on hybrid functionals. We devise a computational methodology to determine the coupling between electrons and phonons during an optical transition in the dilute limit. As a result, our approach yields a smooth spectral function of electron–phonon coupling and includes both quasi-localized and bulk phonons on equal footings. The luminescence lineshape is determined via the generating function approach. We obtain a highly accurate description of the luminescence band, including all key parameters such as the Huang–Rhys factor, the Debye–Waller factor, and the frequency of the dominant phonon mode. More importantly, our work provides insight into the vibrational structure of NV centres, in particular the role of local modes and vibrational resonances. In particular, we find that the pronounced mode at 65 meV is a vibrational resonance, and we quantify localization properties of this mode. These excellent results for the benchmark diamond (NV) centre provide confidence that the procedure can be applied to other defects, including alternative systems that are being considered for applications in quantum information processing.

Double-slit diffraction is a corner stone of quantum mechanics. It illustrates key features of quantum mechanics: interference and the particle-wave duality of matter. In 1965, Richard Feynman presented a thought experiment to show these features. Here we demonstrate the full realization of his famous thought experiment. By placing a movable mask in front of a double-slit to control the transmission through the individual slits, probability distributions for single- and double-slit arrangements were observed. Also, by recording single electron detection events diffracting through a double-slit, a diffraction pattern was built up from individual events.

A visualization scheme for quantum many-body wavefunctions is described that we have termed qubism. Its main property is its recursivity: increasing the number of qubits results in an increase in the image resolution. Thus, the plots are typically fractal. As examples, we provide images for the ground states of commonly used Hamiltonians in condensed matter and cold atom physics, such as Heisenberg or ITF. Many features of the wavefunction, such as magnetization, correlations and criticality, can be visualized as properties of the images. In particular, factorizability can be easily spotted, and a way to estimate the entanglement entropy from the image is provided.

There has been rapid development of systems that yield strong interactions between freely propagating photons in one-dimension via controlled coupling to quantum emitters. This raises interesting possibilities such as quantum information processing with photons or quantum many-body states of light, but treating such systems generally remains a difficult task theoretically. Here, we describe a novel technique in which the dynamics and correlations of a few photons can be exactly calculated, based upon knowledge of the initial photonic state and the solution of the reduced effective dynamics of the quantum emitters alone. We show that this generalized 'input–output' formalism allows for a straightforward numerical implementation regardless of system details, such as emitter positions, external driving, and level structure. As a specific example, we apply our technique to show how atomic systems with infinite-range interactions and under conditions of electromagnetically induced transparency enable the selective transmission of correlated multi-photon states.

We study quantum transport properties of an open Heisenberg XXZ spin 1/2 chain driven by a pair of Lindblad jump operators satisfying a global 'micro-canonical' constraint, i.e. conserving the total magnetization. We will show that this system has an additional discrete symmetry that is specific to the Liouvillean description of the problem. Such symmetry reduces the dynamics even more than would be expected in the standard Hilbert space formalism and establishes existence of multiple steady states. Interestingly, numerical simulations of the XXZ model suggest that a pair of distinct non-equilibrium steady states becomes indistinguishable in the thermodynamic limit, and exhibit sub-diffusive spin transport in the easy-axis regime of anisotropy Δ > 1.

The metascreen-based acoustic passive phased array provides a new degree of freedom for manipulating acoustic waves due to their fascinating properties, such as a fully shifting phase, keeping impedance matching, and holding subwavelength spatial resolution. We develop acoustic theories to analyze the transmission/reflection spectra and the refracted pressure fields of a metascreen composed of elements with four Helmholtz resonators (HRs) in series and a straight pipe. We find that these properties are also valid under oblique incidence with large angles, with the underlying physics stemming from the hybrid resonances between the HRs and the straight pipe. By imposing the desired phase profiles, the refracted fields can be tailored in an anomalous yet controllable manner. In particular, two types of negative refraction are exhibited, based on two distinct mechanisms: one is formed from classical diffraction theory and the other is dominated by the periodicity of the metascreen. Positive (normal) and negative refractions can be converted by simply changing the incident angle, with the coexistence of two types of refraction in a certain range of incident angles.

The leading approach to fault tolerant quantum computing requires a continual supply of magic states. When a new magic state is first encoded, its initial fidelity will be too poor for use in the computation. This necessitates a resource-intensive distillation process that occupies the majority of the computer's hardware; creating magic states with a high initial fidelity minimizes this cost and is therefore crucial for practical quantum computing. Here we present the surprising and encouraging result that raw magic states can have a fidelity significantly better than that of the two-qubit gate operations used to construct them. Our protocol exploits post-selection without significantly slowing the rate of generation and tolerates finite error rates in initializations, measurements and single-qubit gates. This approach may dramatically reduce the size of the hardware needed for a given quantum computing task.

Synchronization is a widespread phenomenon encountered in many natural and engineered systems with nonlinear classical dynamics. How synchronization concepts and mechanisms transfer to the quantum realm and whether features are universal or platform specific are timely questions of fundamental interest. They can be studied in superconducting electrical circuits which provide a well-established platform for nonlinear quantum dynamics. Here, we consider a Josephson-photonics device, where a dc-biased Josephson junction creates (non-classical) light in a microwave cavity. The combined quantum compound constitutes a self-sustained oscillator: a system susceptible to synchronization. This is due to the inherent effect of an in-series resistance, which realizes an autonomous feedback mechanism of the charge transport on the driving voltage. Accounting for the full counting statistics of transported charge not only yields phase diffusion, but allows us to describe phase locking to an ac-signal and the mutual synchronization of two such devices. Thereby one can observe phase stabilization leading to a sharp emission spectrum as well as unique charge transport statistics revealing shot noise induced phase slips. Two-time perturbation theory is used to obtain a reduced description of the oscillators phase dynamics in form of a Fokker–Planck equation in generalization of classical synchronization theories.

We investigate the information extractable from measurement distributions of two non-commuting spin observables in a multi-well spin-1 Bose–Einstein condensate. We provide a variety of analytic and numerical evidence that suitably chosen classical entropies and classical mutual informations thereof contain the typical feature of quantum entropies known in quantum field theories, that is, the area law, even in the non-Gaussian regime and for a non-zero temperature. Towards a feasible experimental implementation, we estimate entropic quantities from a finite number of samples without any additional assumptions on the underlying quantum state using k-nearest neighbor estimators.

We propose a collision model to investigate the information dynamics of a system coupled to an environment with varying degrees of non-Markovianity. We control the degree of non-Markovianity by applying a depolarising channel to a fixed and rigid reservoir of qubits. We characterise the effect of the depolarising channel and apply the model to study the coherent transport of information on a chain of three interacting qubits. We show how the system-environment coupling probability and the degree of non-Markovianity affect the process. Interestingly, in some cases a Markovian environment is preferable to reduce information loss and enhance the coherent transport.

Laser cooling is used to produce ultracold atoms and molecules for quantum science and precision measurement applications. Molecules are more challenging to cool than atoms due to their vibrational and rotational internal degrees of freedom. Molecular rotations lead to the use of type-II transitions ($F \unicode{x2A7E} F^{^{\prime}}$) for magneto-optical trapping (MOT). When typical red detuned light frequencies are applied to these transitions, sub-Doppler heating is induced, resulting in higher temperatures and larger molecular cloud sizes than realized with the type-I MOTs most often used with atoms. To improve type-II MOTs, Jarvis et al (2018 Phys. Rev. Lett.120 083201) proposed a blue-detuned MOT to be applied after initial cooling and capture with a red-detuned MOT. This was successfully implemented (Burau et al 2023 Phys. Rev. Lett.130 193401; Jorapur et al 2024 Phys. Rev. Lett.132 163403; Li et al 2024 Phys. Rev. Lett.132 233402), realizing colder and denser molecular samples. Very recently, Hallas et al (2024 arXiv:2404.03636) demonstrated a blue-detuned MOT with a '1+2' configuration that resulted in even stronger compression of the molecular cloud. Here, we describe and characterize theoretically the conveyor-belt mechanism that underlies this observed enhanced compression. We perform numerical simulations of the conveyor-belt mechanism using both stochastic Schrödinger equation and optical Bloch equation approaches. We investigate the conveyor-belt MOT characteristics in relation to laser parameters, g-factors and the structure of the molecule, and find that conveyor-belt trapping should be applicable to a wide range of laser-coolable molecules.

One of the key technologies in recent quantum devices is the tunable coupling between quantum elements such as qubits, cavities, and waveguides. In this work, we propose a cavity-waveguide tunable coupler realized in a semi-infinite waveguide equipped with a tunable stub. The working principle of the present device is the shift of the node position of the cavity mode induced by the tunable boundary condition at the stub end, and the advantage of the present device is an extremely wide tunability of the cavity-waveguide coupling. When the node position is adjusted to the branch point of the waveguide, the cavity mode becomes decoupled from the waveguide modes in principle. At the same time, owing to the galvanic connection, the present device readily achieves an ultrastrong cavity-waveguide coupling, where the cavity decay rate reaches the order of a gigahertz, comparable to the cavity resonance frequency.

The tetragonal heavy fermion compound CeRh₂As₂ exhibits unconventional superconductivity accompanied by other broken symmetry phases that have been identified as presumably small moment intrinsic antiferromagnetism at low magnetic fields and induced quadrupolar order at higher in-plane fields. The latter may extend to very large pulsed-field range. The phase boundaries can be investigated by following thermodynamic anomalies like specific heat, magnetocaloric coefficient, thermal expansion and magnetostriction. We calculate their discontinuities and identify the influence of the field induced quadrupole on them. Furthermore we investigate the elastic constant anomalies which are determined by the static homogeneous quadrupolar RPA response functions. We present a calculation of these anomalies for the appropriate symmetry mode both in the disordered and ordered regime and investigate their change with applied field. In addition we consider the dynamical momentum dependent magnetic susceptibility and the associated dispersion of low energy magnetic modes and how their characteristics change across the phase boundary.

There are several mathematical formulations of quantum mechanics. The Schrödinger picture expresses quantum states in terms of wavefunctions over, e.g. position or momentum. Alternatively, phase-space formulations represent states with quasi-probability distributions over, e.g. position and momentum. A quasi-probability distribution resembles a probability distribution but may have negative and non-real entries. The most famous quasi-probability distribution, the Wigner function, has played a pivotal role in the development of a continuous-variable quantum theory that has clear analogues of position and momentum. However, the Wigner function is ill-suited for much modern quantum-information research, which is focused on finite-dimensional systems and general observables. Instead, recent years have seen the Kirkwood–Dirac (KD) distribution come to the forefront as a powerful quasi-probability distribution for analysing quantum mechanics. The KD distribution allows tools from statistics and probability theory to be applied to problems in quantum-information processing. A notable difference to the Wigner function is that the KD distribution can represent a quantum state in terms of arbitrary observables. This paper reviews the KD distribution, in three parts. First, we present definitions and basic properties of the KD distribution and its generalisations. Second, we summarise the KD distribution's extensive usage in the study or development of measurement disturbance; quantum metrology; weak values; direct measurements of quantum states; quantum thermodynamics; quantum scrambling and out-of-time-ordered correlators; and the foundations of quantum mechanics, including Leggett–Garg inequalities, the consistent-histories interpretation and contextuality. We emphasise connections between operational quantum advantages and negative or non-real KD quasi-probabilities. Third, we delve into the KD distribution's mathematical structure. We summarise the current knowledge regarding the geometry of KD-positive states (the states for which the KD distribution is a classical probability distribution), describe how to witness and quantify KD non-positivity, and outline relationships between KD non-positivity, coherence and observables' incompatibility.

We investigate known mechanisms for enhancing nuclear fusion rates at ambient temperatures and pressures in solid-state environments. In deuterium fusion, on which the paper is focused, an enhancement of >40 orders of magnitude would be needed to achieve observable fusion. We find that different mechanisms for fusion rate enhancement are known across the domains of atomic physics, nuclear physics, and quantum dynamics. Cascading multiple such mechanisms could lead to an overall enhancement of 40 orders of magnitude or more. We present a roadmap with examples of how hypothesis-driven research could be conducted in—and across—each domain to probe the plausibility of technologically-relevant fusion in the solid state.

Alkali atomic vapor lasers have gained significant attention in recent decades as a promising option for high-powered and efficient laser systems. Utilizing hot alkali atomic vapor as the optical gain medium, these lasers, in principle, offer several advantages, such as high quantum efficiency, reduced thermal issues, and high beam quality. This paper reviews critical techniques developed in recent years to enhance the power and efficiency of these lasers. We discuss continuous wave laser optimization strategies, optical amplifier schemes, and pulsed laser generation based on hot alkali atomic vapor cells. Additionally, select findings from the authors' research group are presented.

Turbulence closure modeling using machine learning (ML) is at an early crossroads. The extraordinary success of ML in a variety of challenging fields had given rise to an expectation of similar transformative advances in the area of turbulence closure modeling. However, by most accounts, the current rate of progress toward accurate and predictive ML-RANS (Reynolds Averaged Navier–Stokes) closure models has been very slow. Upon retrospection, the absence of rapid transformative progress can be attributed to two factors: the underestimation of the intricacies of turbulence modeling and the overestimation of ML's ability to capture all features without employing targeted strategies. To pave the way for more meaningful ML closures tailored to address the nuances of turbulence, this article seeks to review the foundational flow physics to assess the challenges in the context of data-driven approaches. Revisiting analogies with statistical mechanics and stochastic systems, the key physical complexities and mathematical limitations are explicated. It is noted that the current ML approaches do not systematically address the inherent limitations of a statistical approach or the inadequacies of the mathematical forms of closure expressions. The study underscores the drawbacks of supervised learning-based closures and stresses the importance of a more discerning ML modeling framework. As ML methods evolve (which is happening at a rapid pace) and our understanding of the turbulence phenomenon improves, the inferences expressed here should be suitably modified.

Hybrid quantum systems based on magnons in magnetic materials have made significant progress in the past decade. They are built based on the couplings of magnons with microwave photons, optical photons, vibration phonons, and superconducting qubits. In particular, the interactions among magnons, microwave cavity photons, and vibration phonons form the system of cavity magnomechanics (CMM), which lies in the interdisciplinary field of cavity QED, magnonics, quantum optics, and quantum information. Here, we review the experimental and theoretical progress of this emerging field. We first introduce the underlying theories of the magnomechanical coupling, and then some representative classical phenomena that have been experimentally observed, including magnomechanically induced transparency, magnomechanical dynamical backaction, magnon-phonon cross-Kerr nonlinearity, etc. We also discuss a number of theoretical proposals, which show the potential of the CMM system for preparing different kinds of quantum states of magnons, phonons, and photons, and hybrid systems combining magnomechanics and optomechanics and relevant quantum protocols based on them. Finally, we summarize this review and provide an outlook for the future research directions in this field.

The Thouless theory of quantum pumps establishes the conditions for quantized particle transport per cycle, and determines its value. When describing the pump from a moving reference frame, transported and existing charges transform, though not independently. This transformation is inherent to Galilean space and time, but it is underpinned by a transformation of vector bundles. Different formalisms can be used to describe this transformation, including one based on Bloch theory. Depending on the chosen formalism, the two types of charges will be realized as indices of either the same or different kinds. Finally, we apply the bulk-edge correspondence principle, so as to implement the transformation law within Büttiker's scattering theory of quantum pumps.

The composite particle duality extends the notions of both flux attachment and statistical transmutation in spacetime dimensions beyond 2+1D. It constitutes an exact correspondence that can be understood either as a theoretical framework or as a dynamical physical mechanism. The immediate implication of the duality is that an interacting quantum system in arbitrary dimensions can experience a modification of its statistical properties if coupled to a certain gauge field. In other words, commutation relations of quantum fields can be effectively modified by a dynamical physical process. For instance, an originally bosonic quantum fluid in d spatial dimensions can feature composite fermionic (or anyonic) excitations when coupled to a statistical gauge field. In 3+1D the mechanism of flux attachment induces a dynamical formation of dyons as higher-dimensional analogues of Laughlin quasiparticles. In 1+1D there is lack of flux attachment but a remnant in the form of a statistical gauge field can be explicitly constructed. We also introduce a family of interacting quantum many-body systems that undergo statistical transmutation as indicated by the duality. This opens the door to a new realm of topological phases across dimensions both in lattice and continuum systems.

We study spin-dynamics and quantum magnetism with ultracold highly-magnetic atoms. In particular, we focus on the interactions among rare-earth atoms localized in a site of an optical-lattice potential, modeled as a cylindrically symmetric harmonic oscillator in the presence of a weak external magnetic field. The interactions between the atoms are modeled using multi-channel Hamiltonian containing multiple spin-spin and anisotropic spin-orbit interactions with strengths that depend on the separation between the atoms. We studied the eigenenergies of the atom pair in a site for different lattice-site geometries and magnetic field strengths. In parallel, we compared these energies to those found from a simplified approach, where the complex-collisional physics is replaced by a two-length-scale pseudo-potential containing a contact and the magnetic dipole-dipole interaction. The eigenenergies within this model can be computed analytically within the Born approximation as well as non-perturbatively for stronger contact interactions. We have shown that the pseudo-potential model can accurately represent the multi-channel Hamiltonian in certain parameter regimes of the shape or geometry of the site of an optical lattice. The pseudo-potential forms the starting point for many-body, condensed matter simulations involving many atom pairs in different sites of an optical lattice.

The search for quantum algorithms to tackle classical combinatorial optimization problems has long been one of the most attractive yet challenging research topics in quantum computing. In this context, variational quantum algorithms (VQA) are a promising family of hybrid quantum-classical methods tailored to cope with the limited capability of near-term quantum hardware. However, their effectiveness is hampered by the complexity of the classical parameter optimization which is prone to getting stuck either in local minima or in flat regions of the cost-function landscape. The clever design of efficient optimization methods is therefore of fundamental importance for fully leveraging the potential of VQAs. In this work, we approach parameter optimization as a sequential decisionmaking
problem and tackle it with an adaptation of Monte Carlo Tree Search (MCTS), a common artificial intelligence technique designed for efficiently exploring complex decision graphs. We show that leveraging regular parameter patterns deeply affects the decision-tree structure and allows for a flexible and noise-resilient optimization strategy suitable for near-term quantum devices. Our results shed further light on the interplay between artificial intelligence and quantum information and provide a valuable addition to the toolkit of variational quantum circuits.

Current research in statistical mechanics mostly concerns the investigation of out-of-equilibrium, irreversible processes, which are ubiquitous in nature and still far from being theoretically understood. Even the precise characterization of irreversibility is the object of an open debate: while in the context of Hamiltonian systems the one-century-old proposal by M. Smoluchowski looks still valid (a process appears irreversible when the initial state has a recurrence time that is long compared to the time of observation [1]), in dissipative systems, particularly in the case of stochastic processes, the problem is more involved, and quantifying the "degree of irreversibility" is a pragmatic need. The most employed strategies rely on the estimation of entropy production: this quantity, although mathematically well-defined, is often difficult to compute, especially when analyzing experimental data. Moreover, being a global observable, entropy production fails to capture specific aspects of irreversibility in extended systems, such as the role of different currents and their spatial development. This review aims to address various conceptual and technical challenges encountered in the analysis of irreversibility, including the role of the coarse-graining procedure and the treatment of data in the absence of complete information. The discussion will be mostly based on simple models, analytically treatable, and supplemented by examples of complex, more realistic non-equilibrium systems.